The Journal of General Physiology
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The Journal of General Physiology, Vol 18, 171-191, Copyright © 1934 by The Rockefeller University Press

ARTICLE

THE APPLICATION OF QUANTUM MECHANICS TO CERTAIN CASES OF HOMOGENEOUS CATALYSIS. I

Allen E. Stearn 1

1 From the Division of Physical Chemistry, University of Missouri, Columbia

1. The activation energy for the hydrolytic breaking of a peptid linkage has been calculated from quantum mechanical considerations.

2. The relative catalytic effects of H+ and OH- and the mechanism of these effects have been calculated and discussed.

3. These effects are both qualitatively and semiquantitatively in agreement with experiment.

Accepted on April 21, 1934


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